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Fallout: New Vegas Game Add-Ons (DLC) Hints
What else can I get from Daniel now?
1 of 4: Talk to Daniel again and ask if there's any other way you can help the Sorrows. After he says they need healing powder, you can donate some to him for karma increases.
2 of 4: Tell him you need medical assistance, then pay him 150 caps to heal you, 300 caps to remove your rads, or 200 caps to cure an addiction.
3 of 4: Note that it's cheaper to sleep an hour in one of the beds at the camp to heal, and to use the plentiful cave fungus items to remove rads (which you shouldn't be getting many of, anyway). Curing addictions without paying Daniel might be a problem if you don't have a good supply of fixer.
4 of 4: If you tell him you need medical supplies, he'll be reluctant to sell you any. You'll have to pass a Barter 50 or Speech 65 check to gain access to his merchant store.